Reading around, it sounds like there's an exciting condition called "thermal runaway" where a heat-damaged battery becomes short-circuited and can no longer stop itself from overheating. The hottest key was presumably just the most conductive one from the jangling circuit. (Or the least conductive, if it had been a while and it was cooling down less quickly than the others. It's been a while since A-Level Physics.)
You can buy little plastic capsules to store pairs of AA batteries in.
Following kevandotorg's useful comment, I found this information page and now feel more enlightened. However none of this is making me feel any more confident about the rest of the batteries I charged.
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I'd suggest perhaps it wasn't as brief as you think.
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You can buy little plastic capsules to store pairs of AA batteries in.
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http://www.mpoweruk.com/thermal.htm
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