The total mean mass of theEarth's atmosphere is 5.1×1018 kg.
Fraction of this which is CO2: 400 ppm (by volume)
Assume ideal, perfect gases, etc, etc.
Mass of CO2 in atmosphere: 2×1015 kg. (1)
Estimated (2005-06) total coal reserves: 905 GT = 9×1014 kg.
Multiply by (12/14) * (44/12) to convert hydrocarbon (CH2)n to CO2: 2.8 ×1015 kg
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[And that's not even counting the very heat sensitive reserves of methane located on the sea floor and in the permafrost (methane plumes have been spotted up to the thermocline in the summer Atlantic ( ... )
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