I am in the middle of considering what I actually want to be doing for the next N years, and gah. I am afraid that my choices are pretty much (a) do interesting work and work my ass off, no really, and (b) do more physical and less chemical science, which ime is not as enjoyable, and maybe have more reasonable work hours. I don't know how to set
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I wish I had something more useful to say than "good luck!"
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And, yeah, clear expectations are very good.
I think most of the time I've heard of advisors with very strict time-in-lab ideas, they've been in organic chemistry, for what it's worth.
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