I had seen the restaurant chain by that name, and I had seen red-ripened jalapeño peppers sold as "Chipotle" (and had once had the sauce with the buffalo on it) but until this weekend, I had never tried an actual smoke-dried jalapeño (aka chipotle) chile
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Barbecue sauce is vinegar, garlic, some sort of flavoring, and some sort of sweetener (the flavoring apparently varies wildly from place to place, but the most conventional sort is a smoky tomato flavor -- this was the barbecue sauce flavor component that chipotles most reminded me of)
Aioli, conventionally, is vinegar, garlic (as an emulsifier) and olive oil.
In California cuisine, various spices are often added, and it is often used as a vegetable marinade (a canonical recipe of this sort is "grilled artichokes marinated in aioli" -- see
google for more info).
If one uses the same spices for a barbecue sauce and an aioli the difference is that in place of a sweetener, one has an oil.
This makes sense, since most meats contain oil, and one adds sugar to them by marinating in barbecue sauce -- as most vegetables contain sugar and little to no oil, it is logical to use aioli instead.
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The "Chipotle" restaurant chain is owned by the McDonalds corporation. For that reason, I have avoided them to date. I don't know if the food is good or not.
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I also do not recall ever having been to a Chipotle's. Apparently they make a sauce which uses Chipotles.
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