These have in common that they can sound impossible at first description, even (or perhaps especially) to seasoned puzzlers and/or people with some mathematical knowledge. In all cases, if I were presented with them for the first time and asked "either do this or provide a proof that it's mathematically impossible", I'd be inclined to start working
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2: I can't completely get it but this almost works: Ahzore gur fdhnerf 1 gb 64, nqq gur inyhrf bs gur fdhnerf jvgu urnqf ba, nqwhfg n pbva fb gung gur gbgny zbq 64 vf gur gnetrg fdhner. Ohg V'z abg fher lbh pna nyjnlf qb guvf orpnhfr lbh zvtug jnag gb nqq 23 ohg 23 vf nyernql n urnqf. Srryf yvxr gur evtug genpx gubhtu
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5, if you want it: An infinite number of mathematicians will each be given a hat. They'll be able to see everyone's hats except for their own. They each have to simultaneously guess their own hat colour. Is there a strategy such that only finitely many of them will be wrong?
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5: Cool, that's definitely in the same category of puzzles that initially look completely impossible!
Are there any constraints on the hat colours? Or can they be any colour from the (extremely large, but presumably finite for quantum-ish reasons) number of distinct wavelengths in the visible light spectrum?
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(Also, the solution requires the axiom of choice and isn't remotely something an infinite number of real people could actually do)
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Pbafvqre nyy cbffvoyr nffvtazragf bs ungf gb crbcyr. Qrsvar nffvtazragf nf rdhvinyrag vs gurl qvssre sbe ng zbfg svavgryl znal crbcyr. (Guvf vf n erny rdhvinyrapr eryngvba, vs nffvtazragf N naq O ner rdhvinyrag, naq O naq P ner, gura N naq P nyfb zhfg or). Fb lbh pna cnegvgvba gur frg bs cbffvoyr nffvtazragf vagb rdhvinyrapr pynffrf. Va gur cer-tnzr fgengrtl zrrgvat, rirelbar nterrf ba n ercerfragngvir nffvtazrag sbe rnpu rdhvinyrapr pynff (guvf arrqf gur nkvbz bs pubvpr naq lbh pbhyqa'g npghnyyl qb guvf va erny yvsr...).
Gura, bapr rirelbar frrf gur ungf, gurl pna gryy juvpu rdhvinyrapr pynff gurl'er va (orpnhfr gurl pna frr nyy ohg n svavgr ahzore (bar) bs gur ungf). Gura rirelbar thrffrf nppbeqvat gb gur nffvtazrag gurl pubfr.
Fb (vasvavgryl ynetr) fgengrtl ybbxf yvxr "Vs gur ung nffvtazrag lbh frr vf bayl qvssrerag sebz 'nyy oynpx' sbe n svavgr ahzore bs crbcyr, thrff oynpx. Vs vg'f bayl svavgryl qvssrerag sebz 'nygreangvat benatr naq checyr', thrff onfrq ba gung. rgp rgp
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I'll be curious to hear what the intended answer for #4 is. I've got an answer, but I don't think it can be the one the puzzle designer intended, because: vg bayl arrqf sbhe bs gur svir cynlref. Vg fhssvprf gb unir gjb ebjf bs gjb cynlref rnpu snpvat rnpu bgure. Fb gur guveq cynlre va bar bs gur ebjf pna or pbzcyrgryl vtaberq, va gur frafr gung abar bs gur bgure sbhe cynlref' qrpvfvbaf vf nssrpgrq ol gur rkgen cynlre'f ung pbybhe, naq bar bs gur bgure sbhe jvyy eryvnoyl thrff evtug, fb vg jbhyqa'g rira znggre vs cynlre svir unf fhcerzryl onq yhpx naq nyjnlf thrffrf jebat ( ... )
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#1': Oh, cool. Yes, I think they can: vs gurer'f n plpyr ybatre guna svsgl, fjnc gjb qvnzrgevpnyyl bccbfvgr obkrf jvguva vg, yvxr gur "zvqqyr" bar naq gur "ynfg" bar, gb fcyvg vg vagb gjb plpyrf unys gur fvmr.
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On that assumption, I think I've got an answer that does significantly better than the totally obvious 50-50 guesswork strategy - but I'm absolutely nowhere near thinking of a way to prove it's the best possible!
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But my solution definitely depends on the choice being random rather than directed. In an adversarial situation where someone was listening to our strategy session and then choosing the hats to defeat it, they would have no trouble doing so, and then we'd all be on uncertain-goat-guard duty for sure.
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I think that's true in any of these puzzles where you're looking to maximise your chance of success rather than guarantee it (e.g. the 100 prisoners one without your addition of a sympathetic prison guard).
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